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Updated: Jul 14, 2026

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Integrating a Triplet-triplet Annihilation Up-conversion System to Enhance Dye-sensitized Solar Cell Response to Sub-bandgap Light
Published on: September 12, 2014
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Chemical modification of temoporfin--a second generation photosensitizer activated using upconverting nanoparticles
Q Yu1, E M Rodriguez, R Naccache
1Department of Chemistry and Biochemistry, Concordia University, Montreal, Canada. John.Capobianco@concordia.ca.
Abstract:
LiYF4:Tm(3+)/Yb(3+) upconverting nanoparticles (UCNPs) were functionalized with the second generation photosensitizer 5,10,15,20-tetra(m-hydroxyphenyl)chlorin (m-THPC, Temoporfin, Foscan®). m-THPC was modified using 4-(bromomethyl)benzoic acid, which induced a bathochromic shift of the m-THPC blue absorption peak. The nanoconstruct causes up to 70% cell death under 980 nm irradiation.

