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New classes of ferromagnetic materials with exclusively end-on azido bridges: from single-molecule magnets to 2 D
Dimitris I Alexandropoulos1, Luís Cunha-Silva, Albert Escuer
1Department of Chemistry, Brock University, L2S 3A1 St. Catharines, Ontario (Canada).
Abstract:
A new, flexible synthetic route, which does not require the co-presence of any organic chelating/bridging ligand but only the "key" precursor Me3SiN3, has been discovered and led to a new class of inorganic materials containing exclusively end-on azido bridges; the reported 3d-metal clusters and coordination polymers exhibit ferromagnetic, single-molecule magnet, and long-range magnetic ordering properties.
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