Related Experiment Video
Updated: Apr 23, 2026

Synthesis of pH Dependent Pyrazole, Imidazole, and Isoindolone Dipyrrinone Fluorophores using a Claisen-Schmidt Condensation Approach
Published on: June 10, 2021
Ring-shaped silafluorene derivatives as efficient solid-state UV-fluorophores: synthesis, characterization, and
Yuanjing Cai1, Kerim Samedov, Brian S Dolinar
1School of Materials Science and Engineering, Wuhan University of Technology, Wuhan 430070 (P. R. China); Department of Chemistry, University of Wisconsin-Madison, 1101 University Ave., Madison Wisconsin 53706 (USA), Fax: (+1) 608-265-6815.
Abstract:
Four ring-shaped silafluorene-containing compounds (1-4) were synthesized and characterized as potentially promising monomers for fluorescent polymers. Their optical properties in solution and solid state (thin film and powder) were studied. These compounds have low quantum yields in solution (Φ(fl)=0.13-0.15) with fluorescence maxima at about 355 nm, but high quantum yields in the solid state (powder, Φ(fl)=0.35-0.54) with fluorescence maxima at about 377 and 488 nm. Influence of the substituents and the number of silafluorene units in 1-4 on their optical properties was investigated. Extensive study of the X-ray crystal structures of 1-4 was undertaken to analyze and qualitatively estimate the role, extent, and influence of silafluorene moieties' interactions on solid-state fluorescent properties. Excited state UV/Vis and theoretical molecular orbital (MO) calculations were performed to explore possible fluorescence mechanisms and differences in quantum yields among these compounds.
More Related Videos
08:51Scale-up Chemical Synthesis of Thermally-activated Delayed Fluorescence Emitters Based on the Dibenzothiophene-S,S-Dioxide Core
Published on: October 24, 2017
12:07Microwave-assisted Intramolecular Dehydrogenative Diels-Alder Reactions for the Synthesis of Functionalized Naphthalenes/Solvatochromic Dyes
Published on: April 1, 2013
Related Concept Videos
Variables Affecting Phosphorescence and Fluorescence
Photoluminescence: Applications
Photoluminescence: Fluorescence and Phosphorescence
A pair of electrons in a...
Fluorescence and Phosphorescence: Instrumentation