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Carbon monoxide in controlling the surface formation of Group VIII metal nanoparticles
Sang Youp Hwang1, Mingzhen Zhang, Changlin Zhang
1Department of Chemical and Biomolecular Engineering, University of Akron, Akron, OH 44325, USA. zpeng@uakron.edu.
Abstract:
Group VIII metal nanoparticles with variant morphologies were synthesized under a carbon monoxide atmosphere. The important roles of CO in determining the surface formation of growing particles were studied both by experiment and density functional theory (DFT) calculations, which suggest different growth mechanisms for these metals.
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