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A Simple and Efficient Protocol for the Catalytic Insertion Polymerization of Functional Norbornenes
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A Simple and Efficient Protocol for the Catalytic Insertion Polymerization of Functional Norbornenes

Published on: February 27, 2017

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Polymerization of norbornene using chiral bis(phenolate) zirconium catalysts

Marie Tschage1, Seungwhan Jung, Thomas P Spaniol

  • 1RWTH Aachen University, Institute of Inorganic Chemistry, Landoltweg 1, 52056, Aachen, Germany.

Macromolecular Rapid Communications
|October 2, 2014
PubMed
Summary

Zirconium catalysts with bis(phenolate) ligands enable the polymerization of norbornene, yielding high molecular weight polymers. Enantiopure catalysts demonstrate optical induction, with microstructure analysis aided by copolymers and hydrooligomers.

Keywords:
crystalline oligo(norbornene)ethylene-norbornene copolymersnon-metallocene catalystsnorbornene polymerizationoptically active polymers

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