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Updated: Apr 23, 2026

Self-assembling Morphologies Obtained from Helical Polycarbodiimide Copolymers and Their Triazole Derivatives
Published on: February 7, 2017
Communication: Molecular-level insights into asymmetric triblock copolymers: network and phase development
Syamal S Tallury1, Kenneth P Mineart2, Sebastian Woloszczuk3
1Department of Materials Science and Engineering, North Carolina State University, Raleigh, North Carolina 27695, USA.
Abstract:
Molecularly asymmetric triblock copolymers progressively grown from a parent diblock copolymer can be used to elucidate the phase and property transformation from diblock to network-forming triblock copolymer. In this study, we use several theoretical formalisms and simulation methods to examine the molecular-level characteristics accompanying this transformation, and show that reported macroscopic-level transitions correspond to the onset of an equilibrium network. Midblock conformational fractions and copolymer morphologies are provided as functions of copolymer composition and temperature.
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