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Direct evidence for catalase activity of [Ru(V)(edta)(O)](-)
Debabrata Chatterjee1, Namita Jaiswal, Alicja Franke
1Chemistry and Biomimetics Group, CSIR-Central Mechanical Engineering Research Institute, MG Avenue, Durgapur-713209, India. dchat57@hotmail.com.
Abstract:
Reported is the first example of a ruthenium(III) complex, Ru(III)(edta) (edta(4-) = ethylenediaminetetraacetate), that catalyzes the disproportion of H2O2 to O2 and water in resemblance to catalase activity, and shedding light on the possible mechanism of action of the [Ru(V)(edta)(O)](-) formed in the reacting system.
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