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Published on: February 5, 2019
Bottom-up preparation of MgH₂ nanoparticles with enhanced cycle life stability during electrochemical conversion in
Yassine Oumellal1, Claudia Zlotea, Stéphane Bastide
1Institut de Chimie et des Matériaux Paris-Est, CNRS UPEC UMR 7182, 2-8 rue Henri Dunant, 94320 Thiais, France. claudia.zlotea@icmpe.cnrs.fr.
Abstract:
A promising anode material for Li-ion batteries based on MgH₂ with around 5 nm average particles size was synthesized by a bottom-up method. A series of several composites containing MgH₂ nanoparticles well dispersed into a porous carbon host has been prepared with different metal content up to 70 wt%. A narrow particle size distribution (1-10 nm) of the MgH₂ nanospecies with around 5.5 nm average size can be controlled up to 50 wt% Mg. After a ball milling treatment under Ar, the composite containing 50 wt% Mg shows an impressive cycle life stability with a good electrochemical capacity of around 500 mA h g(-1). Moreover, the nanoparticles' size distribution is stable during cycling.

