Related Experiment Video
Updated: Apr 21, 2026

Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
Published on: July 30, 2017
N-heterocyclic carbene-main-group chemistry: a rapidly evolving field
Yuzhong Wang1, Gregory H Robinson
1Department of Chemistry, The University of Georgia , Athens, Georgia 30602-2556, United States.
Abstract:
This Award Article targets the evolving, yet surprisingly fruitful, chemistry of N-heterocyclic carbenes with low-oxidation-state main-group elements. Specifically, the chemistry of carbene-stabilized diatomic allotropes, diborenes, gallium octahedra, beryllium borohydride, and a host of related compounds will be presented. Providing a valuable historical perspective, the foundational work concerning the organometallic chemistry of gallium with sterically demanding m-terphenyl ligands from this laboratory will also be discussed.
Related Concept Videos
Five-Membered Heterocyclic Aromatic Compounds: Overview
Aromatic Hydrocarbon Cations: Structural Overview
Removing one hydrogen from the intervening CH2 group...
Carbocations
Properties of Organometallic Compounds
ortho–para-Directing Activators: –CH3, –OH, –⁠NH2, –OCH3
Basicity of Heterocyclic Aromatic Amines

