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A Standard and Reliable Method to Fabricate Two-Dimensional Nanoelectronics
Published on: August 28, 2018
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Ultrathin two-dimensional inorganic materials: new opportunities for solid state nanochemistry
Yongfu Sun1, Shan Gao, Fengcai Lei
1Hefei National Laboratory for Physical Sciences at the Microscale and Collaborative Innovation Center of Chemistry for Energy Materials, University of Science and Technology of China , Hefei, Anhui 230026, People's Republic of China.
Accounts of Chemical Research
|December 10, 2014
Summary
Solid state nanochemistry advances by studying ultrathin 2D inorganic materials. These materials enable clear structure-property relationships, linking atomic, defect, and electronic structures to material properties.
Area of Science:
- Solid State Chemistry
- Nanochemistry
- Materials Science
Background:
- Conventional solid state chemistry focuses on bulk materials.
- Nanocrystals present challenges in correlating structure and properties due to complex microstructures.
- Atomically thin 2D inorganic materials offer a unique platform for precise structure-property relationship studies.
Purpose of the Study:
- To establish clear correlations between atomic, defect, and electronic structure and the intrinsic properties of solid state materials.
- To highlight the potential of ultrathin 2D inorganic materials in solid state nanochemistry.
- To review recent advances in characterizing these materials and their properties.
Main Methods:
- X-ray absorption fine structure (XAFS) spectroscopy for atomic structure characterization.
- Positron annihilation spectra and electron spin resonance for defect characterization.
- Density-functional calculations for electronic structure investigation.
Main Results:
- Detailed atomic structures, including coordination number and bond length, were characterized.
- Various structural defects and their impact on physicochemical properties were identified.
- Explicit relationships between structure (atomic, defect, electronic) and properties (optoelectronic, electrical, magnetic, thermal) were established.
Conclusions:
- Ultrathin 2D inorganic materials are ideal for advancing solid state nanochemistry.
- Precise structure-property relationships can be established using advanced characterization techniques.
- Future opportunities lie in leveraging these materials for new discoveries in solid state nanochemistry.

