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Updated: Apr 19, 2026

Synthesis of a Thiol Building Block for the Crystallization of a Semiconducting Gyroidal Metal-sulfur Framework
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General and practical formation of thiocyanates from thiols

Reto Frei1, Thibaut Courant, Matthew D Wodrich

  • 1Present address: Bern University of Applied Sciences, Solothurnstrasse 102, 2504 Biel (Switzerland).

Chemistry (Weinheim an Der Bergstrasse, Germany)
|December 19, 2014
PubMed
Summary

A novel method enables rapid, room-temperature synthesis of thiocyanates from thiols and disulfides using hypervalent iodine reagents. This efficient cyanation reaction offers broad applications in synthetic chemistry and materials science.

Keywords:
chemoselectivitycyanationhypervalent iodinesynthetic methodsthiocyanates

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