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Organotemplate-free synthesis of an open-framework magnesium aluminophosphate with proton conduction properties
1State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China. lijiyang@jlu.edu.cn jihong@jlu.edu.cn.
Chemical Communications (Cambridge, England)
|January 3, 2015
Abstract:
A new open-framework magnesium aluminophosphate MgAlP2O7(OH)(H2O)2 (denoted as JU102) has been hydrothermally synthesized by using an organotemplate-free synthetic route in the Al2O3-P2O5-MgO-H2O system. JU102 exhibits novel 4-connected zeolite-like topology with 8-ring channels. The existence of coordinated water and extensive H-bonds in the structure endows JU102 with unique proton conduction properties.
