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Updated: Apr 18, 2026

Spatial Separation of Molecular Conformers and Clusters
Published on: January 9, 2014
Polar stacking of molecules in liquid chloroform
J J Shephard1, A K Soper, S K Callear
1Department of Chemistry, University College London, 20 Gordon Street, WC1H 0AJ London, UK. c.salzmann@ucl.ac.uk.
Abstract:
Using neutron diffraction and the isotopic substitution technique we have investigated the local structure of liquid chloroform. A strong tendency for polar stacking of molecules with collinear alignment of dipole moments is found. We speculate that these polar stacks contribute to the performance of chloroform as a solvent.
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