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A fluorescent heteroditopic hemicryptophane cage for the selective recognition of choline phosphate
Dawei Zhang1, Guohua Gao, Laure Guy
1Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, 3663 North Zhongshan Road, Shanghai, 200062, P. R. China. ghgao@chem.ecnu.edu.cn.
Chemical Communications (Cambridge, England)
|January 10, 2015
Abstract:
The first fluorescent hemicryptophane cage was synthesized and developed as an efficient and selective sensor for choline phosphate. The heteroditopic character of the host in the recognition process was evidenced. NMR experiments highlight a full encapsulation of the guest, inducing the chiralisation-like behavior of the achiral choline phosphate.
