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Light-driven Enzymatic Decarboxylation
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The gold(i)-catalysed protodecarboxylation mechanism.

Stéphanie Dupuy1, Luke Crawford, Michael Bühl

  • 1EastCHEM, School of Chemistry, University of St. Andrews, North Haugh, St. Andrews, Fife, KY16 9ST (UK).

Chemistry (Weinheim an Der Bergstrasse, Germany)
|January 13, 2015
PubMed
Summary

This study details the gold-catalyzed protodecarboxylation mechanism. Researchers found that protodeauration can compete with decarboxylation, a switch influenced by pKa.

Keywords:
N-heterocyclic carbenesdecarboxylationgoldmechanismprotodeauration

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