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Author Spotlight: Accelerating Discovery in Microporous Material Chemistry
Published on: October 6, 2023
Multiarylpolycarboxylate-mediated hybrid cobalt phosphate frameworks with supramolecular zeolitic topology and
Qing-Rong Ding1, Li-Ming Li, Lei Zhang
1State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences , Fuzhou, Fujian 350002, P. R. China.
Abstract:
Two novel organic-inorganic hybrid frameworks containing multiarylpolycarboxylate linkers and cobalt phosphate layers, [H2DABCO]·[Co(HPO4)(bpdc)] (1) and [H2DABCO]3·[Co10(npa)3(PO4)6Cl2] (2), where bpdc = 4,4'-biphenyldicarboxylate, npa = 2,6-naphthalenedicarboxylate, and DABCO = 1,4-diazabicyclo[2.2.2]octane, have been solvothermally synthesized. Compound 1 features a 3D zeolite-like supramolecular network with ABW topology, and compound 2 is a 3D framework structure with unusual I(2)O(2) connectivity.
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