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Updated: Apr 18, 2026

Facile Preparation of 2Z,4E-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
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Initial radical cation pathway in the Mo2Cl10-mediated dehydrogenative arene coupling.

Jana Leppin1, Moritz Schubert, Siegfried R Waldvogel

  • 1Institute of Inorganic Chemistry and Analytical Chemistry, Johannes Gutenberg-University of Mainz, Duesbergweg 10-14, 55128 Mainz (Germany).

Chemistry (Weinheim an Der Bergstrasse, Germany)
|January 30, 2015
PubMed
Summary

Molybdenum complexes catalyze arene coupling by forming radical cations from methoxyarenes. This initial electron transfer occurs through an inner sphere mechanism, providing key mechanistic insights.

Keywords:
CC couplingEPR spectroscopyelectron transfermolybdenumradical cations

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