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[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
Published on: May 21, 2019
The copper(I) metal azolate framework showing unusual coordination mode for the 1,2,4-triazole derivative and
Bai-Qiao Song1, Chao Qin, Yu-Teng Zhang
1Institute of Functional Material Chemistry, Key Laboratory of Polyoxometalate Science of Ministry of Education, Northeast Normal University, Changchun, 130024 Jilin, People's Republic of China. wangxl824@nenu.edu.cn zmsu@nenu.edu.cn.
Abstract:
A unique three-dimensional metal azolate framework containing a tetranuclear copper cluster constructed by six 1,2,4-triazole units was synthesized in which the 1,2,4-triazole units show unusual bridging "crevice" coordination mode with their 1- and 2-positioned sp(2) N-atoms as symmetrically bridging centers. The photocatalytic activities of as-prepared compound were tested by degradation of rhodamine-B (RB) under different light irradiation.
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