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Preparation of Biomass-based Mesoporous Carbon with Higher Nitrogen-/Oxygen-chelating Adsorption for CuII Through Microwave Pre-Pyrolysis
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N-doped microporous carbons derived from direct carbonization of K+ exchanged meta-aminophenol-formaldehyde resin for
Jin Zhou1, Zhaohui Li, Wei Xing
1School of Chemical Engineering, Shandong University of Technology, Zibo 255049, P. R. China. zhuosp_academic@yahoo.com.
Chemical Communications (Cambridge, England)
|February 18, 2015
Abstract:
N-doped microporous carbons with uniform ultramicropores (∼0.50 nm) are facilely prepared by direct carbonization of K(+) exchanged meta-aminophenol-formaldehyde resin. These materials give an unprecedented CO2 uptake of 1.67 mmol g(-1) at 25 °C and 0.15 bar and superior CO2-over-N2 selectivity (50 : 1).
