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CO2 Hydrogenation Catalyzed by Iridium Complexes with a Proton-Responsive Ligand

Naoya Onishi1,2, Shaoan Xu1,2, Yuichi Manaka1

  • 1†National Institute of Advanced Industrial Science and Technology, Tsukuba Central 5, 1-1-1 Higashi, Tsukuba, Ibaraki 305-8565, Japan.

Inorganic Chemistry
|February 19, 2015
PubMed
Summary

Iridium complexes with hydroxy-functionalized ligands efficiently catalyze carbon dioxide (CO2) hydrogenation for hydrogen storage. These ligands enhance catalytic activity through electronic and secondary coordination sphere effects, enabling efficient CO2 conversion at room temperature.

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