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Preparation of Highly Porous Coordination Polymer Coatings on Macroporous Polymer Monoliths for Enhanced Enrichment of Phosphopeptides
Published on: July 14, 2015
Controlled formation of fluorescent metalloporphyrin-containing coordination polymer particles from seed structures
Yu Sun1, Xiaopeng Li, Alessio Caravella
1School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing (USTB), Xueyuan Road 30, Beijing, 100083 (P. R. China). sunyu1983@ustb.edu.cn.
Abstract:
Herein, nanorod structures and four-leaf clover structures of fluorescent zinc 5,10,15,20-tetra(4-pyridyl)-21H,23H-porphine (ZnTPyP)-containing coordination polymer particles (CPPs) were first synthesized by a bottom-up strategy assisted by surfactants and then employed as seed structures for further shape-transformation reactions. We have successfully designed the morphological transformation for different dimensions, achieving the controlled formation of octahedron structures at both the nanometer scale and micrometer scale from the seed structures. Our approach illustrates a new method to design and synthesize metalloporphyrin-containing CPPs in a systematic and controllable manner.

