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Published on: November 11, 2013
A scalable hybrid separator for a high performance lithium-sulfur battery
Lina Wang1, Jingyuan Liu, Servane Haller
1Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Institute of New Energy, and Collaborative Innovation Center of Chemistry for Energy Materials, Fudan University, Shanghai 200433, China. ygwang@fudan.edu.cn yyxia@fudan.edu.cn.
A new hybrid separator enhances lithium-sulfur (Li-S) battery performance for over 500 cycles using standard sulfur cathodes. This innovation significantly reduces the polysulfide shuttle effect, paving the way for practical Li-S battery applications.
Area of Science:
- Materials Science
- Electrochemistry
- Energy Storage
Background:
- Lithium-sulfur (Li-S) batteries offer high theoretical energy density but suffer from performance degradation.
- The polysulfide shuttle effect is a major challenge limiting the practical application of Li-S batteries.
Purpose of the Study:
- To develop and integrate a novel hybrid separator for improved Li-S battery performance.
- To investigate the effectiveness of the hybrid separator in mitigating the polysulfide shuttle and enhancing cycle life.
Main Methods:
- Design and fabrication of a hybrid separator combining glassy fiber paper and a microporous membrane.
- Integration of the hybrid separator into Li-S battery cells.
- Electrochemical performance testing, including cycling stability up to 500 cycles.
Main Results:
- The hybrid separator effectively restrained the polysulfide shuttle process.
- Superior cell performance was achieved, with stable cycling for up to 500 cycles.
- The battery utilized commercially available pristine sulfur as the cathode material.
Conclusions:
- The newly designed hybrid separator is a promising component for practical Li-S battery applications.
- This separator technology significantly improves the cycle life and stability of Li-S batteries.
- The study highlights a viable strategy to overcome key limitations in Li-S battery technology.

