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In situ Grazing Incidence Small Angle X-ray Scattering on Roll-To-Roll Coating of Organic Solar Cells with Laboratory X-ray Instrumentation
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Simple O2 plasma-processed V2O5 as an anode buffer layer for high-performance polymer solar cells.

Xichang Bao1, Qianqian Zhu2, Ting Wang1

  • 1†CAS Key Laboratory of Bio-based Materials, Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao 266101, China.

ACS Applied Materials & Interfaces
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PubMed
Summary

A simple oxygen (O2) plasma method creates an efficient vanadium oxide (V2O5) anode buffer layer for polymer solar cells (PSCs). This O2 plasma-processed V2O5 layer significantly boosts power conversion efficiencies (PCEs) in PSCs.

Keywords:
O2 plasma processingV2O5annealing-freeanode buffer layerefficient polymer solar cells

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Area of Science:

  • Materials Science
  • Renewable Energy
  • Organic Electronics

Background:

  • Polymer solar cells (PSCs) require efficient anode buffer layers to optimize performance.
  • Indium tin oxide (ITO) is a common substrate, but its interfacial properties can limit device efficiency.

Purpose of the Study:

  • To develop a simple and effective oxygen (O2) plasma processing method for creating vanadium oxide (V2O5) anode buffer layers.
  • To investigate the impact of this O2 plasma-processed V2O5 layer on the performance of PSCs.

Main Methods:

  • Spin coating a vanadium(V) triisopropoxide oxide alcohol solution onto ITO-coated glass.
  • Treating the coated layer with O2 plasma for 10 minutes to form the V2O5 anode buffer layer.
  • Fabricating and testing PSCs with the V2O5 (O2 plasma) layer using P3HT:PC61BM and PBDTTT-C:PC71BM active layers.

Main Results:

  • The V2O5 (O2 plasma) layer exhibited high transmittance and favorable electrical and interfacial properties.
  • PSCs utilizing the V2O5 (O2 plasma) buffer layer achieved power conversion efficiencies (PCEs) of 4.47% and 7.54% for the respective active layers.
  • Compared to control devices, PCEs were improved by 15.6% (for PSS) and 20.2% (for thermally annealed V2O5), attributed to enhanced fill factor and short-circuit current density.

Conclusions:

  • O2 plasma-processed V2O5 is an efficient, economical anode buffer layer for high-performance PSCs.
  • The improved performance is linked to modifications in work function, increased dangling bonds for better interfacial contact, and excellent charge transport.
  • This method offers a promising route for low-cost fabrication of organic electronic devices.