Related Experiment Video
Updated: Apr 15, 2026

Self-assembling Morphologies Obtained from Helical Polycarbodiimide Copolymers and Their Triazole Derivatives
Published on: February 7, 2017
Self-assembly in aqueous solution of amphiphilic graft copolymers from oxidized carboxymethylcellulose
Eduardo Bordallo1, Jacques Rieumont2, Marcio José Tiera3
1Cuban Research Institute of Sugar Cane, Havana, Cuba; Department of Chemistry and Environmental Science, Institute of Biosciences, Humanities, and Exact Science (IBILCE), San Paulo University (UNESP), San Paulo, SP, Brazil; Center for Research in Biological Chemistry and Molecular Materials (CIQUS), University of Santiago de Compostela, A Coruña, Spain.
Abstract:
A series of oxidized carboxymethylcellulose-graft-poly(ethylene glycol)-dodecylamine (OCMC-g-PEG-DDA) was prepared by using an appositely prepared PEG with terminal amino groups and different amounts of DDA. The nanoaggregates formed in aqueous solution were characterized by surface tension measurements, fluorescence spectroscopy, dynamic light scattering (DLS) and scanning electron microscopies (SEM and TEM). The micelles showed narrow hydrodynamic size distributions and diameters varying from 163 to 193nm depending on the ratio of DDA to PEG chains. The DDA content in the graft copolymers also affected the core-shell interfacial compactness.
More Related Videos
11:42Synthesis of Monodisperse Cylindrical Nanoparticles via Crystallization-driven Self-assembly of Biodegradable Block Copolymers
Published on: June 20, 2019
07:39Facile Synthesis of Worm-like Micelles by Visible Light Mediated Dispersion Polymerization Using Photoredox Catalyst
Published on: June 8, 2016
Related Concept Videos
Anionic Chain-Growth Polymerization: Overview
Anionic Chain-Growth Polymerization: Mechanism
Cationic Chain-Growth Polymerization: Mechanism
Characteristics and Nomenclature of Copolymers
Step-Growth Polymerization: Overview
Many natural and synthetic polymers are produced by...