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Photooxidizing chromium catalysts for promoting radical cation cycloadditions

Susan M Stevenson1, Matthew P Shores2, Eric M Ferreira3

  • 1Department of Chemistry, University of Georgia, Athens, GA 30602 (USA).

Angewandte Chemie (International Ed. in English)
|April 16, 2015
PubMed
Summary

Selected chromium(III) complexes act as photocatalysts, initiating radical cation cycloadditions by oxidizing electron-rich alkenes. These novel metal catalysts offer unique reactivity in photoredox reactions, expanding beyond traditional ruthenium and iridium systems.

Keywords:
chromiumcycloadditionoxidationphotocatalysisradical cations

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