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Axial ligand substitution in a microperoxidase-derived peptide enables P450-like electrocatalysis
Koji Nakano1, Sae Uezato1, Hikari Nagadome1
1Department of Applied Chemistry, Faculty of Engineering, Kyushu University 744 Motooka, Nishi-ku Fukuoka 819-0395 Japan k.nakano.qq@adm.fukuoka-u.ac.jp.
None:
A histidine-to-cysteine substituted minimal haem peptide exhibited P450-like electrocatalysis under direct electrochemical control. The immobilised peptide catalysed substrate oxidation on a gold electrode, consistent with a peroxide-shunt-type mechanism.
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