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Updated: Apr 14, 2026

A Novel Technique for Generating and Observing Chemiluminescence in a Biological Setting
Published on: March 9, 2017
Excited state investigation of a new Ru(II) complex for dual reactivity with low energy light
J D Knoll1, B A Albani, C Turro
1Department of Chemistry and Biochemistry, The Ohio State University, Columbus, Ohio 43210, USA. turro.1@osu.edu.
Abstract:
The new complex [Ru(tpy)(Me2dppn)(py)](2+) efficiently photodissociates py in CH3CN with Φ500 = 0.053(1) induced by steric bulk from methyl substituents and produces (1)O2 with ΦΔ = 0.69(9) from its long-lived (3)ππ* excited state. The unique excited state processes that result in dual reactivity were investigated using ultrafast transient absorption spectroscopy.
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