A highly robust metal-organic framework based on an aromatic 12-carboxyl ligand with highly selective adsorption of
Hongming He1, Yang Song, Chuanqi Zhang
1State Key laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun, 130012, China. fxsun@jlu.edu.cn.
Chemical Communications (Cambridge, England)
|May 12, 2015
Abstract:
A highly robust MOF based on a 12-carboxyl dendritic aromatic ligand and two Cd clusters is successfully synthesized. This activated MOF exhibits high heat of absorption of CO2 and highly selective adsorption of CO2 over CH4. Especially, a new type of topology (hhm-a) is presented.
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