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Two-step solid-state synthesis of PEPPSI-type compounds
Christopher J Adams1, Matteo Lusi, Emily M Mutambi
1School of Chemistry, University of Bristol, Bristol, BS8 1TS, UK.
Chemical Communications (Cambridge, England)
|May 15, 2015
Abstract:
The two-step mechanochemical preparation of carbene-pyridine complexes of palladium and platinum is reported. The organometallic products, which represent a class of commercially available catalysts, are rapidly formed in excellent yield proving solvent-free synthesis to be a viable synthetic alternative even in the case of NHC-containing compounds.
