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A simple approach to the synthesis of Cu1.8S dendrites with thiamine hydrochloride as a sulfur source and

Xiaoliang Yan1, Sha Li2, Yun-Xiang Pan3

  • 1College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024, P. R. China.

Beilstein Journal of Nanotechnology
|May 16, 2015
PubMed

Keywords:
Cu1.8S dendritebiomaterialscrystal growthcrystal structurehydrothermal

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Preparation and Reactions of Thiols02:33

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Thiols are prepared using the hydrosulfide anion as a nucleophile in a nucleophilic substitution reaction with alkyl halides. For instance, bromobutane reacts with sodium hydrosulfide to give butanethiol.
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Sulfides are the sulfur analog of ethers, just as thiols are the sulfur analog of alcohol. Like ethers, sulfides also consist of two hydrocarbon groups bonded to the central sulfur atom. Depending upon the type of groups present, sulfides can be symmetrical or asymmetrical. Symmetrical sulfides can be prepared via an SN2 reaction between 2 equivalents of an alkyl halide and one equivalent of sodium sulfide.
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Thiols and sulfides are sulfur analogs of alcohols and ethers, respectively, where the sulfur atom takes the place of the oxygen atom. Thus, thiols are generally represented as RSH, where R is an alkyl substituent and —SH is the functional group. On the other hand, in sulfides, the central sulfur atom is bonded to two hydrocarbon groups on either side. Depending upon the type of group, sulfides can be either symmetrical or asymmetrical. Both thiols and sulfides display a bent geometry,...
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