Enzymatic synthesis and post-functionalization of two-dimensional crystalline cellulose oligomers with
Yusuke Yataka1, Toshiki Sawada, Takeshi Serizawa
1Department of Organic and Polymeric Materials, Tokyo Institute of Technology, 2-12-1-H121 Ookayama, Meguro-ku, Tokyo 152-8550, Japan. serizawa@polymer.titech.ac.jp.
Abstract:
Two-dimensional (2D) nanomaterials have gained considerable attention due to their unique structural and physicochemical properties. Herein, we synthesized 2D crystalline cellulose oligomers with surface-reactive azide groups through enzymatic reactions and covalently post-functionalized them with 1-ethynyl pyrene through copper(i)-catalyzed Huisgen cycloaddition reactions.
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