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Hybrid materials of Ni NP@MOF prepared by a simple synthetic method
Megumi Mukoyoshi1, Hirokazu Kobayashi, Kohei Kusada
1Division of Chemistry, Graduate School of Science, Kyoto University, Kitashirakawa-Oiwakecho, Sakyo-ku, Kyoto 606-8502, Japan. hkobayashi@kuchem.kyoto-u.ac.jp kitagawa@kuchem.kyoto-u.ac.jp.
Abstract:
We demonstrate a novel, simple synthetic method for metal (Ni) NPs in a MOF using the partial thermal decomposition of nickel(II) 2,5-dihydroxyterephthalate (Ni-MOF-74). The Ni NPs inside the Ni-MOF-74 are several nanometers in size, and the size can be precisely controlled by the heating conditions.

