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Updated: Apr 7, 2026

Facile Preparation of 2Z,4E-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
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Facile Preparation of 2Z,4E-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate

Published on: June 21, 2017

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Gold-catalyzed intramolecular diazo coupling: an efficient macrocyclization towards cyclic olefins

Chenghao Zhu1, Guangyang Xu, Kai Liu

  • 1School of Pharmaceutical Engineering & Life Science, Changzhou University, Changzhou 213164, P. R. China. jtsun08@gmail.com.

Chemical Communications (Cambridge, England)
|July 14, 2015
PubMed
Summary

Gold catalysis enables efficient synthesis of cyclic olefins from diazo compounds. Olefin selectivity is tunable by ligand structure and ring size, avoiding harsh reaction conditions.

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