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Graphenes as Efficient Metal-Free Fenton Catalysts
Juan C Espinosa1, Sergio Navalón1, Ana Primo1
1Instituto de Tecnología Química CSIC-UPV and Departamento de Química, Univ. Politécnica de Valencia, Av. de los Naranjos s/n, 46022 Valencia (Spain).
Abstract:
Reduced graphene oxide exhibits high activity as Fenton catalyst with HO(.) radical generation efficiency over 82 % and turnover numbers of 4540 and 15023 for phenol degradation and H2 O2 consumption, respectively. These values compare favorably with those achieved with transition metals, showing the potential of carbocatalysts for the Fenton reaction.
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