Chlorinated herbicides in fish, birds and mammals in the Baltic Sea

The aim of the present work was to determine the concentration levels, as well as accumulation and magnification coefficients, of triazine derivatives in herring gulls and Baltic grey seals 11 years after a ban on their use in the EU and eight after their exclusion in Poland. Dead birds were collected in the coastal zone of the Gulf of Gdansk in the years 2010-2012. The grey seals, on the other hand, were from before 2007, when s-triazine derivatives were still in use. Triazine herbicides (atrazine, simazine, propazine, terbutrine, prometrone, prometrine and ametrine) were found in the muscles and livers of birds and mammals and also in fish. The obtained results indicated the presence of all the assayed triazines in whole Baltic herring and their livers, while fish muscles were found to be free of prometrone and ametrine. In the muscles and liver of the grey seal, no ametrine, propazine or terbutrine were found, while prometrine was found in the liver of only one specimen. Research showed that simazine did not accumulate and magnify in marine birds and mammals. Atrazine became accumulated in the liver of birds and mammals while magnification was determined in their muscles. The accumulation of ametrine was found in the muscles of seals.