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Ferromagnetism01:31

Ferromagnetism

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Materials like iron, nickel, and cobalt consist of magnetic domains, within which the magnetic dipoles are arranged parallel to each other. The magnetic dipoles are rigidly aligned in the same direction within a domain by quantum mechanical coupling among the atoms. This coupling is so strong that even thermal agitation at room temperature cannot break it. The result is that each domain has a net dipole moment. However, some materials have weaker coupling, and are ferromagnetic at lower...
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Color in Coordination Complexes
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human...
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Related Experiment Video

Updated: Apr 5, 2026

Stable Aqueous Suspensions of Manganese Ferrite Clusters with Tunable Nanoscale Dimension and Composition
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Ferric Phosphate Hydroxide Microstructures Affect Their Magnetic Properties.

Junhong Zhao1, Youjuan Zhang1, Zhen Run1

  • 1College of Chemistry and Chemical Engineering, Anyang Normal University Anyang, Henan, 455002, P. R. China.

Chemistryopen
|August 7, 2015
PubMed
Summary

Uniformly sized ferric phosphate hydroxide (Fe4(OH)3(PO4)3) microstructures were synthesized. Controlling reaction conditions precisely tuned particle size and morphology, influencing magnetic properties like blocking temperature.

Keywords:
blocking temperatureferric phosphate hydroxidehydrothermal conditionmagnetic propertiesmicrostructures

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Area of Science:

  • Materials Science
  • Nanotechnology
  • Solid State Chemistry

Background:

  • Uniformly sized and shape-controlled nanoparticles are crucial for applications in catalysis, electrochemistry, ion exchange, molecular adsorption, and electronics.
  • Ferric phosphate hydroxide (Fe4(OH)3(PO4)3) is a functional material with potential applications influenced by its structure.

Purpose of the Study:

  • To synthesize ferric phosphate hydroxide (Fe4(OH)3(PO4)3) microstructures with controlled size and morphology.
  • To investigate the relationship between the micro/nanostructure morphology and the magnetic properties of Fe4(OH)3(PO4)3.

Main Methods:

  • Hydrothermal synthesis of Fe4(OH)3(PO4)3 microstructures.
  • Controlled variations in reaction time, temperature, and CTAB concentration to tune morphology.
  • Characterization of particle size, shape, and magnetic properties, including blocking temperature (T B).

Main Results:

  • Fe4(OH)3(PO4)3 microcrystals were successfully prepared under hydrothermal conditions.
  • Hyperbranched microcrystals formed at 180°C (without CTAB), while monodisperse particles formed at 220°C (with CTAB).
  • Magnetic properties, specifically blocking temperature (T B), showed a direct correlation with particle size and morphology, with smaller sizes yielding lower T B.

Conclusions:

  • Precise control over the morphology of Fe4(OH)3(PO4)3 microstructures is achievable by adjusting hydrothermal synthesis conditions.
  • The physical and chemical properties, particularly magnetic behavior, are intrinsically linked to the material's structure.
  • Tailoring the morphology of functional nanomaterials offers a pathway to control their performance in various applications.