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Enzymatic Synthesis of Epoxidized Metabolites of Docosahexaenoic, Eicosapentaenoic, and Arachidonic Acids
Published on: June 28, 2019
Total synthesis of the natural product EBC-329
Raju S Thombal1, Vrushali H Jadhav1
1Division of Organic Chemistry, National Chemical Laboratory (CSIR-NCL), Pune-411008, India. vh.jadhav@ncl.res.in.
Abstract:
The first total synthesis of an anti-leukemic diterpene natural product EBC-329 (1) has been accomplished starting from readily available 6,6-dimethyl-3-oxabicyclo[3.1.0]hexane-2,4-dione (7). An efficient and general approach has been reported for the synthesis of EBC-329 in 13 steps with an overall yield of 10%.
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