High-Resolution Photocurrent Imaging of Bulk Heterojunction Solar Cells

Images obtained from photocurrent scanning of organic bulk heterojunction solar cell devices provide a direct measure of correlation of the morphology to the performance parameters. The peripheral photocurrent induced from light coupled to probe tips in the near-field regime of bulk heterojunction layers permits in situ scanning of active solar cells with asymmetric electrodes. We present a methodology involving a combination of atomic force microscopy, near-field optical microscopy, and near-field photocurrent microscopy to decipher the carrier generation and transport regions in the bulk heterojunction layer. The angular Fourier transformation technique is implemented on these images to rationalize the optimum blend concentration in crystalline and amorphous donor systems and provide insights into the role of the bulk heterojunction morphology.