Experimental investigation of circular Bragg phenomenon for oblique incidence

A 20-period-thick chiral sculptured thin film (STF) of zinc selenide was fabricated on a glass slide by thermal evaporation. A variable-angle spectroscopic system was devised and used to measure all eight of the circular remittances of the chiral STF as functions of the angle of incidence and the free-space wavelength. Thereby, the center wavelength and the bandwidth of the circular Bragg phenomenon exhibited by structurally chiral materials such as cholesteric liquid crystals and chiral STFs were comprehensively characterized for incidence angles in the range [0°,70°]. The experimental data were qualitatively compared with data calculated using a helicoidal model for the relative permittivity dyadic of the chiral STF, and assuming that all three eigenvalues of that dyadic obey the single-resonance Lorentz model. The chosen representation was found adequate to represent the blue shift of the centerwavelength with an increasing angle of incidence, but the Lorentz model requires modification to develop improved predictive capabilities.