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A Low Reabsorbing Luminescent Solar Concentrator Employing π-Conjugated Polymers
Gregory D Gutierrez1, Igor Coropceanu1, Moungi G Bawendi1
1Department of Chemistry, Massachusetts Institute of Technology, Cambridge, MA, 02139, USA.
Abstract:
A highly efficient thin-film luminescent solar concentrator (LSC) utilizing two π-conjugated polymers as antennae for small amounts of the valued perylene bisimide Lumogen F Red 305 is presented. The LSC exhibits high photoluminescence quantum yield, low reabsorption, and relatively low refractive indices for waveguide matching. A Monte Carlo simulation predicts the LSC to possess exceptionally high optical efficiencies on large scales.
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