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Aromaticity of Diazaborines and Their Protonated Forms

Milovan Stojanović1, Marija Baranac-Stojanović2

  • 1Center for Chemistry ICTM, University of Belgrade , Njegoševa 12, P.O.Box 473, 11000 Belgrade, Serbia.

The Journal of Organic Chemistry
|December 2, 2015
PubMed

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Arenediazonium substitution reactions occur when the diazonium group is substituted by various functional groups such as halides, hydroxyl, nitrile, etc. For instance, arenediazonium salts react with copper(I) salts of chloride, bromide, or cyanide to form corresponding aryl chlorides, bromides, and nitriles. These reactions are named Sandmeyer reactions. Although the mechanism of this reaction is complicated, as illustrated in Figure 1, they are believed to progress via an aryl copper...
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