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Surface Modification of Polymers by Reaction of Alkyl Radicals
Dardan Hetemi1,2, Jérôme Médard1, Frédéric Kanoufi1
1Univ Paris Diderot, Sorbonne Paris Cité, ITODYS, UMR 7086 CNRS , 15 rue J-A de Baïf, 75205 Paris Cedex 13, France.
Abstract:
The surfaces of poly(methyl methacrylate) and polyethylene are modified either (i) by a two-step process including the thermal reaction of alkyl radicals derived from bromohexanoic acid in a mixture of 2,6-dimethylbenzene diazonium salt and neat isopentyl nitrite at 60 °C, followed by reaction with p-nitroaniline, anthraquinone, neutral red, and polyethylene glycol moieties, or (ii) by reaction of a previously anthraquinone-modified bromohexanoic acid. The modified surfaces are characterized by IR, XPS, UV, and water contact angles. A mechanism is proposed to rationalize the results. This approach is an efficient way to modify and pattern polymer surfaces with different organic groups and chemical functionalities under mild conditions.
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