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Updated: Mar 28, 2026

Self-assembling Morphologies Obtained from Helical Polycarbodiimide Copolymers and Their Triazole Derivatives
Published on: February 7, 2017
Chirality induction using circularly polarized light into a branched oligofluorene derivative in the presence of an
Yue Wang1, Alexander L Kanibolotsky2, Peter J Skabara3
1Institute for Catalysis (ICAT) and Graduate School of Chemical Sciences and Engineering, Hokkaido University, N 21, W 10, Kita-ku, Sapporo 001-0021, Japan. tamaki.nakano@cat.hokudai.ac.jp.
Abstract:
Chirality induction into a uniform, star-shaped fluorene oligomer with a central truxene moiety (T3) was achieved using circularly polarized light in the presence of achiral fluorene or phenanthrene. Induction into T3 alone was difficult, suggesting that close chain packing realized through interactions of T3 with small molecules plays a role in chirality induction.
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