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Updated: Mar 28, 2026

Scale-up Chemical Synthesis of Thermally-activated Delayed Fluorescence Emitters Based on the Dibenzothiophene-S,S-Dioxide Core
Published on: October 24, 2017
Creating a thermally activated delayed fluorescence channel in a single polymer system to enhance exciton utilization
Jiajia Luo1, Guohua Xie1, Shaolong Gong1
1Hubei Collaborative Innovation Center for Advanced Organic Chemical Materials, Hubei Key Lab on Organic and Polymeric Optoelectronic Materials, Department of Chemistry, Wuhan University, Wuhan, 430072, People's Republic of China. clyang@whu.edu.cn.
Abstract:
We designed and synthesized a single polymer with TADF characteristics by grafting the TADF emitter, 10-(4-(5-phenyl-1,3,4-oxadiazol-2-yl)phenyl)-10H-phenoxazine, onto the side chain of the polymer backbone of polycarbazole. Employing these copolymers as emitting layers, an efficient bluish-green polymer LED with a maximum external quantum efficiency of 4.3% was achieved, corresponding to a high exciton utilization efficiency (EUE) of 63.7%.
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