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Application of Elemental Lanthanides in the Selective C-F Activation of Trifluoromethylated Benzofulvenes Providing Access to Various Difluoroalkenes
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Application of Elemental Lanthanides in the Selective C-F Activation of Trifluoromethylated Benzofulvenes Providing Access to Various Difluoroalkenes

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Carbon-carbon bond cleavage for Cu-mediated aromatic trifluoromethylations and pentafluoroethylations

Tsuyuka Sugiishi1, Hideki Amii1, Kohsuke Aikawa2

  • 1Division of Molecular Science, Faculty of Science and Technology, Gunma University, 1-5-1 Tenjin-cho, Kiryu, Gunma 376-8515, Japan.

Beilstein Journal of Organic Chemistry
|January 7, 2016
PubMed

Keywords:
carbon–carbon bond cleavagedecarboxylationfluoraltetrahedral intermediatetrifluoroacetatetrifluoromethylationβ-carbon elimination

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