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Controlled Flexible Coordination in Tripodal Iron(II) Phosphane Complexes: Effects on Reactivity

Anette Petuker1, Klaus Merz1, Christian Merten1

  • 1Inorganic Chemistry I and ‡Physical Organic Chemistry, Ruhr University Bochum , Universitätsstraße 150, 44801 Bochum, Germany.

Inorganic Chemistry
|January 12, 2016
PubMed
Summary

Replacing carbon with silicon in tripodal ligands alters iron complex properties and reactivity. This C/Si exchange offers a straightforward method to tune metal complex behavior without significant steric changes, impacting coordination and catalytic activity.

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