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Synthesis and Structural Studies of Gallium(III) and Iron(III) Hemicryptophane Complexes
Isabelle Gosse1, Koen Robeyns2, Catherine Bougault3
1Laboratoire de Chimie, École Normale Supérieure de Lyon, CNRS, UCBL , 46 allée d'Italie, F-69364 Lyon 7, France.
Abstract:
New gallium(III) and iron(III) endohedral complexes were obtained from a hemicryptophane ligand bearing suitable binding sites for octahedral metal coordination. The solid-state structures of the free host and of the complexes were determined by single-crystal X-ray diffraction analysis. The metal ion is linked to the hydrazone nitrogen and the phenolate oxygen atoms, yielding a distorted octahedral geometry around the encapsulated metal. The two isomorphous structures of the metal complexes reveal the exclusive formation of PΔ/MΛ enantiomeric pairs.
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