A new rhodamine-based colorimetric chemosensor for naked-eye detection of Cu(2+) in aqueous solution
Yang Hu1, Jing Zhang2, Yuan-Zheng Lv1
1Hubei Key Laboratory of Pollutant Analysis & Reuse Technology, Department of Chemical and Environmental Engineering, Hubei Normal University, Huangshi 435002, PR China.
Abstract:
A new colorimetric probe 1 based on rhodamine B lactam was developed for naked-eye detection of Cu(2+). The optical feature of 1 for Cu(2+) was investigated by UV-vis absorption spectroscopy. Upon the addition of Cu(2+), the 1 displayed a distinct color change from colorless to pink, which can be directly detected by the naked eye. The stoichiometry of 1 to Cu(2+) complex was found to be 1:1 and the naked-eye detection limit was determined as low as 2 μM. The results suggest that the probe 1 may provide a convenient method for visual detection of Cu(2+) with high sensitivity.


