A photoluminescent indium-organic framework with discrete cages and one-dimensional channels for gas adsorption
Jinjie Qian1, Qipeng Li2, Linfeng Liang3
1College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou 325035, China. jinjieqian@wzu.edu.cn smhuang@wzu.edu.cn and State Key Laboratory of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China.
Chemical Communications (Cambridge, England)
|January 20, 2016
Abstract:
We have successfully obtained, for the first time, a new heterometallic indium-organic framework (InOF-14) with a functional and luminescent Eu(iii) component. Based on the mutually competitive [In(CO2)4] and [Eu2(CO2)4(H2O)4] units, this microporous structure possesses discrete nano-cages and one-dimensional channels for gas adsorption, and simultaneously exhibits excellent luminescence properties.
