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Isolating Free Carbenes, their Mixed Dimers and Organic Radicals
Published on: April 19, 2019
Hypoelectronic isomeric diiridaboranes [(Cp*Ir)2B6H6]: the "Rule-Breakers"(Cp* = η(5)-C5Me5)
Rosmita Borthakur1, Bijan Mondal1, Purbasha Nandi1
1Department of Chemistry, Indian Institute of Technology Madras, Chennai, 600036, India. sghosh@iitm.ac.in.
Abstract:
In an effort to synthesize supraicosahedral iridaboranes, pyrolysis of [Cp*IrCl2]2 with excess [BH3·] was carried out, and this synthesis afforded the isomeric iridaborane [(Cp*Ir)2B6H6] clusters 1 and 2. The geometry of 1 was determined to be dodecahedral, i.e., similar to that of [B8H8](2-), whereas 2 was found to exhibit a cluster shape that can be derived from a nine-vertex tricapped trigonal prism by removing one of the capped vertices. The calculation of a large HOMO-LUMO gap further rationalized the isocloso structures for these isomers.
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